Oxide evolution on Alloy X-750 in simulated BWR environment

Autor: Fang Liu, Kenneth Göransson, Krystyna Marta Stiller, Seikh Mohammad Habibur Rahman, Mattias Thuvander, Sten Eriksson, Silvia Tuzi
Rok vydání: 2016
Předmět:
Zdroj: Journal of Nuclear Materials. 482:19-27
ISSN: 0022-3115
Popis: In order to simulate the environment experienced by spacer grids in a boiling water reactor (BWR), specimens of the Ni-based Alloy X-750 were exposed to a water jet in an autoclave at a temperature of 286 degrees C and a pressure of 80 bar. The oxide microstructure of specimens exposed for 2 h, 24 h, 168 h and 840 h has been investigated mainly using electron microscopy. The specimens suffer mass loss due to dissolution during exposure. At the same time a complex layered oxide develops. After the longest exposure the oxide consists of two outer spinel layers consisting of blocky crystals, one intermediate layer of nickel oxide interspersed with Ti-rich oxide needles, and an inner layer of oxidized base metal. The evolution of the oxide leading up to this structure is discussed and a model is presented.
Databáze: OpenAIRE