Preparation of magnesium borohydride and diborane

Autor: J. P. Faust, S. Papetti, H. D. Batha, T. L. Heying, E. D. Whitney
Rok vydání: 2007
Předmět:
Zdroj: Journal of Applied Chemistry. 12:478-481
ISSN: 1934-998X
0021-8871
DOI: 10.1002/jctb.5010121102
Popis: A good yield (97%) of MgBH4 is obtained by interaction of magnesium hydrides with diborane in a glycol ether medium or a mixture of glycol ether and benzene (1:3) at 80°. Interaction of the borohydride with boron trichloride in benzene at ∼80° gives a 94% yield of diborane.
Databáze: OpenAIRE