Preparation of magnesium borohydride and diborane
Autor: | J. P. Faust, S. Papetti, H. D. Batha, T. L. Heying, E. D. Whitney |
---|---|
Rok vydání: | 2007 |
Předmět: | |
Zdroj: | Journal of Applied Chemistry. 12:478-481 |
ISSN: | 1934-998X 0021-8871 |
DOI: | 10.1002/jctb.5010121102 |
Popis: | A good yield (97%) of MgBH4 is obtained by interaction of magnesium hydrides with diborane in a glycol ether medium or a mixture of glycol ether and benzene (1:3) at 80°. Interaction of the borohydride with boron trichloride in benzene at ∼80° gives a 94% yield of diborane. |
Databáze: | OpenAIRE |
Externí odkaz: |