Phenylated poly(P-phenylene vinylenes) prepared via the chlorine precursor route (CPR)

Autor:	Bing R. Hsieh, William A. Feld, Yongli Gao, Stevan A. Gonzalez, Thomas E. Goodwin, Wai Chou Wan
Rok vydání:	1998
Předmět:	chemistry.chemical_classification Polymers and Plastics Organic Chemistry chemistry.chemical_element Polymer Condensed Matter Physics chemistry.chemical_compound Monomer chemistry Polymerization Poly(p-phenylene) Polymer chemistry Materials Chemistry Chlorine Organic synthesis Thin film Benzene
Zdroj:	Macromolecular Symposia. 125:205-211
ISSN:	1022-1360
DOI:	10.1002/masy.19981250119
Popis:	The synthesis of several highly phenylated PPV derivatives by a chlorine precursor route (CPR) was investigated in order to understand its scope. Three 1,4-bis(chloromethyl)benzene monomers were prepared via a robust and versatile synthetic procedure involving the Diels-Alder reaction. The monomers were then polymerized to the corresponding precursor polymers with about 1.0 equivalent of potassium t-butoxide in THF. Only one monomer gave a soluble precursor polymer while the other two gave insoluble precursor polymers. The soluble precursor polymer was deposited as thin films and then converted to the corresponding PPV derivative, which showed green photoluminesence and electroluminesence.
Databáze:	OpenAIRE
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