CaCl2- or MgCl2-Catalyzed Allylic Oxidations of Ionone-Like Dienes

Autor:	Min Yang, Ru-Gang Xie, Jingbo Lan, Qian-Rong Peng, Guang-Fu Song
Rok vydání:	2007
Předmět:	Terpene Allylic rearrangement chemistry.chemical_compound chemistry Organic chemistry General Medicine Ionone Catalysis
Zdroj:	ChemInform. 38
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200707057
Popis:	The allylic oxidation of ionone-like dienes catalyzed by CaCl 2 or MgCl 2 with TBHP is presented. The method provides a facile method to synthesize dienones derived from ionone-like dienes in good to moderate yields. A plausible mechanism for the oxidation is proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c08894856487530b8217c56b042e6c8b https://doi.org/10.1002/chin.200707057 Zobrazit plný text záznamu Plný text