Click-formed polymer gels with aggregation-induced emission and dual stimuli-responsive behaviors

Autor:	Guo-ying Zhang, Sheng-yu Shi
Rok vydání:	2021
Předmět:	chemistry.chemical_classification Solvent chemistry.chemical_compound chemistry Stimuli responsive Chemical engineering Trifluoroacetic acid Click chemistry Tetraphenylethylene Polymer Physical and Theoretical Chemistry Aggregation-induced emission Fluorescence
Zdroj:	Chinese Journal of Chemical Physics. 34:365-372
ISSN:	2327-2244 1674-0068
DOI:	10.1063/1674-0068/cjcp2006090
Popis:	Stimuli-responsive polymer gels have recently attracted great attention due to their heat/solvent resistance, dimensional stability, and unique sensitivity to external stimuli. In this work, we synthesized thiol-functionalized tetraphenylethylene (TPE) and constructed polymer gels through thiol-ene click reaction. The synthetic process of the polymer gels could be monitored by fluorescence emission of TPE moieties based on aggregation-induced emission mechanism. In addition, due to the dual redoxand acid responsiveness of the polymer gels, in the presence of dithiothreitol and trifluoroacetic acid, fluorescence quenching of the polymer gels can be observed. This stimuli-responsive characteristics endows the polymer gels with potential applications in fluorescent sensing and imaging, cancer diagnosis and selfhealing materials.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c07ca3998528313e6ed31f396383ce83 https://doi.org/10.1063/1674-0068/cjcp2006090 Zobrazit plný text záznamu