Aquapentakis(1H-imidazole-κN3)nickel(II) dibromosuccinate

Autor:	Ying-Jue Shen, Le Sun, Yuan Xiao, Juan Wang, Ze-Zhao Hua, Dai-Xi Li
Rok vydání:	2005
Předmět:	Chemistry Hydrogen bond Stereochemistry Stacking chemistry.chemical_element Atom (order theory) General Chemistry Condensed Matter Physics Ion Nickel Crystallography chemistry.chemical_compound Imidazole General Materials Science Isostructural Cobalt
Zdroj:	Acta Crystallographica Section E Structure Reports Online. 61:m2145-m2147
ISSN:	1600-5368
DOI:	10.1107/s1600536805030084
Popis:	The title compound, [Ni(C3H4N2)5(H2O)](C4H2Br2O4), consists of NiII complex cations and dibromo­succinate anions. The Ni atom, water O atom and one imidazole N atom of the complex cation lie on a twofold axis. The anion lies on an inversion centre. The crystal packing is reinforced by O—H⋯O and N—H⋯O hydrogen bonds, but there are no π–π stacking inter­actions even though the complex contains five aromatic imidazole rings. The compound is isostructural with its cobalt analogue.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c06531e201bd79f7abb4acafc85e9579 https://doi.org/10.1107/s1600536805030084 Zobrazit plný text záznamu Plný text ve formátu PDF