One-pot solvent-free reductive amination with a solid ammonium carbamate salt from CO2 and amine

Autor:	Philjun Kang, Nam Hwi Hur, Won Koo Lee, Kyu Myung Lee, Kyu Hyung Lee, Jaeheung Cho, Byeongno Lee
Rok vydání:	2014
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Solvent free Chemistry General Chemical Engineering Carbon dioxide Organic chemistry Ammonium carbamate Salt (chemistry) Amine gas treating General Chemistry Reductive amination
Zdroj:	RSC Adv.. 4:46203-46207
ISSN:	2046-2069
DOI:	10.1039/c4ra07558g
Popis:	Many amines are liquid and their handling is inconvenient compared with the corresponding solids. We transformed a liquid (S)-(−)-1-phenylethylamine 1 to the corresponding neutral solid form 2 by reacting with carbon dioxide. We performed reductive amination of 2 with various aldehydes 3 under solvent-free conditions to provide secondary amines 5 in high yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c03cc35b8cced4cc0d63c53370cabe92 https://doi.org/10.1039/c4ra07558g Zobrazit plný text záznamu