Structural Conformation of a Novel Piperidine-4-One Derivative: 1-Acryloyl-3-Methyl-2,6-Dip-Tolylpiperidine-4-One

Autor: C. R. Gnanendra, Nagaraja Naik, B. N. Lakshminarayana, T. N. Mahadeva Prasad, M. A. Sridhar, J. Shashidhara Prasad, D. Chenne Gowda
Rok vydání: 2010
Předmět:
Zdroj: Journal of Chemical Crystallography. 40:686-690
ISSN: 1572-8854
1074-1542
DOI: 10.1007/s10870-010-9722-x
Popis: The novel 3-methyl-2,6-dip-toylpiperidine-4-one was acylated by 3-chloropropanoychloride and subjected for dehydrohalogenation. The synthesized compound was characterized by spectroscopic techniques and finally confirmed by X-ray diffraction studies. The molecule crystallizes in the monoclinic crystal class in the space group C 2/c with cell parameters a = 18.538(2) A, b = 9.9050(1) A, c = 22.954(2) A, β = 94.486(8)° and Z = 8. The piperidine ring adopts a twist boat conformation. The title compound was synthesized by acylation of 3-methyl-2,6-dip-tolylpiperidin-4-one followed by dehydrohalogenation and recrystalisation in ethanol. The molecule crystallizes in the monoclinic crystal class in the space group C2/c with cell parameters a = 18.538(2)A, b = 9.9050(1) A, c = 22.954(2) A, β = 94.486(8)° and Z = 8. The heterocyclic ring adopts a twisted boat conformation.
Databáze: OpenAIRE
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