Two pairs of enantiomeric α-pyrone dimers from the endophytic fungus Phoma sp. YN02-P-3

Autor:	Shao-Fei Chen, Hai-Feng Wang, Jiao Bai, Xiao-Jie Lu, Xiao An, Dan Zhao, Xia-Nan Sang, Yue-Hu Pei, Gang Chen, Sheng-Ge Li
Rok vydání:	2017
Předmět:	biology 010405 organic chemistry Stereochemistry Chemistry General Chemical Engineering General Chemistry Endophytic fungus 010402 general chemistry biology.organism_classification Ring (chemistry) 01 natural sciences Pyrone 0104 chemical sciences chemistry.chemical_compound Phoma Enantiomer
Zdroj:	RSC Advances. 7:1943-1946
ISSN:	2046-2069
DOI:	10.1039/c6ra26319d
Popis:	(±) Phomones A (1) and B (2), two pairs of novel enantiomeric α-pyrone dimers from the endophytic fungus Phoma sp. YN02-P-3 are reported. Compounds 1 and 2 are the first examples of 6-α,β-unsaturated ester-2-pyrone dimers, and compound 1 possesses a novel 6/4/5/6 tetracyclic ring system. Their structures and stereochemistry were determined by the analysis of extensive spectroscopic data, ECD calculations and single-crystal X-ray diffraction data.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::c01a8731187110d570bddf8de6c9ea80 https://doi.org/10.1039/c6ra26319d Zobrazit plný text záznamu