Experimental and calculated electronic structure of gaseous CrO2F2 and CrO2Cl2
| Autor: | Jerry P. Jasinski, Smith L. Holt, Larned B. Asprey, J. H. Wood |
|---|---|
| Rok vydání: | 1975 |
| Předmět: |
Absorption spectroscopy
Chemistry Atomic electron transition Non-bonding orbital Excited state General Physics and Astronomy Molecular orbital Electronic structure Physical and Theoretical Chemistry Atomic physics Molecular physics Molecular electronic transition Ultraviolet photoelectron spectroscopy |
| Zdroj: | The Journal of Chemical Physics. 63:757-771 |
| ISSN: | 1089-7690 0021-9606 |
| Popis: | The gas phase electronic absorption spectra of CrO2F2 and CrO2Cl2 have been measured in the visible, near ultraviolet regions. Interpretation has been made by comparison with a molecular orbital calculation for each molecule by the SCF‐Xα‐SW method. The calculated ground and excited states and observed electronic transitions correlate directly with those for the parent isoelectronic CrO2−4 and MnO−4 species. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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