Stereochemical investigation of the reaction of cyclopentadienyl(diphosphine)methoxycarbeneruthenium(II) complexes with LiAlH4
| Autor: | Giambattista Consiglio, Franco Morandini, Felix Bangerter |
|---|---|
| Rok vydání: | 1985 |
| Předmět: |
Organic Chemistry
chemistry.chemical_element Nuclear magnetic resonance spectroscopy Photochemistry Biochemistry Medicinal chemistry Ruthenium law.invention Inorganic Chemistry chemistry.chemical_compound Cyclopentadienyl complex chemistry law Alkane stereochemistry Atom Materials Chemistry Physical and Theoretical Chemistry Walden inversion Carbene |
| Zdroj: | Journal of Organometallic Chemistry. 293:c29-c32 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(85)80310-7 |
| Popis: | [(η-C5H5)Ru{Ph2PCHRCHR′PPh2}({C(OCH3)CH2C6H5})]PF6 (where R, R′ = H or CH3) reacts with LiAlH4 in THF at −80° C to give the corresponding 2-phenylethyl complexes, which have an antiperiplanar conformation around the H2CCH2 bond in solution; the reaction takes place with retention of configuration at the ruthenium atom. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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