THE THERMAL DECOMPOSITION OF PLUTONIUM HEXAFLUORIDE1

Autor:	R. K. Steunenberg, W. A. Shinn, L. E. Trevorrow
Rok vydání:	1961
Předmět:	Inorganic chemistry Thermal decomposition General Engineering Analytical chemistry chemistry.chemical_element Plutonium hexafluoride Decomposition Plutonium chemistry.chemical_compound Plutonium tetrafluoride chemistry Fluorine Physical and Theoretical Chemistry Equilibrium constant Stoichiometry
Zdroj:	The Journal of Physical Chemistry. 65:398-403
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100821a003
Popis:	Stoichiometric and equilibrium determinations were made of the thermal decomposition reaction of plutonium hexafluoride at temperatures from 150 to 400 deg . The reaction products under these conditions were gaseous fluorine and solid plutonium tetrafluoride. Below 300 deg , the equilibnium constants (moles PuF/sub 2//moles F/sub 2/) were found to be higher than literature values. The sharp change in the relation between log K and l/T at 308 deg reported previously was not found in the present work. The relation between equilibrium constant and temperature is expressed by the equation log K = -1331/T( deg K) - 0.275. (auth)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bffd0460467529b9b49929dbd7c8b81e https://doi.org/10.1021/j100821a003 Zobrazit plný text záznamu