Structural Confinement Effects of an Amorphous Magneto-Semiconductor within Nanochannels

Autor:	Jin Seung Jung, Leszek Malkinski, Weon-Sik Chae, C. J. O’Connor, Kyoung Hoon Choi, Yong Rok Kim
Rok vydání:	2006
Předmět:	Potential well Spin glass Nanocomposite Condensed matter physics Phonon Chalcogenide business.industry General Chemistry Amorphous solid Condensed Matter::Materials Science chemistry.chemical_compound Semiconductor chemistry business Superparamagnetism
Zdroj:	Journal of the Chinese Chemical Society. 53:209-217
ISSN:	0009-4536
Popis:	Optical and magnetic properties have been investigated for the structurally confined amorphous magneto-semiconductor, ternary chalcogenide, within the nanochannels of the mesoporous host. The structural confinement induced a weak crystallographic ordering of the magneto-semiconductor within the nanochannels. Unique optical properties were observed for this nanocomposite, which were possibly due to the size and energy quantization of the confined guest chalcogenide within the nanochannels. The structural confinement also induced the suppression of the phonon coupling to the photoexcited carriers during the carriers' recombination process. The spin-glass freezing temperature (T f = 4.2 K) which was the characteristic magnetic transition temperature for the amorphous bulk was shifted to 2.3 K for the confined system, possibly due to the generation of the superparamagnetic domains induced by the quantum confinement effect.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bfd5e1e90b919fd6064a2031c8484949 https://doi.org/10.1002/jccs.200600023 Zobrazit plný text záznamu Plný text