The electrochemical properties of LiCl-KCl melt held in contact with samarium

Autor:	A. V. Kovalevskii, O. V. El’kin
Rok vydání:	2011
Předmět:	Materials science Inorganic chemistry Substrate (chemistry) chemistry.chemical_element Electrochemistry Chloride Metal Samarium Nickel chemistry Oxidation state visual_art visual_art.visual_art_medium medicine Physical and Theoretical Chemistry Equilibrium constant medicine.drug
Zdroj:	Russian Journal of Physical Chemistry A. 85:499-502
ISSN:	1531-863X 0036-0244
DOI:	10.1134/s0036024411030204
Popis:	The dependence of the reaction capacity (R) of a LiCl (60 mol %)-KCl melt held in contact with samarium at 873 and 973 K on the concentration of the corroding metal in the melt was obtained. The R value was used to estimate the content of Sm2+ ions in the lowest oxidation state, their fraction, and the conventional equilibrium constant of the 2Sm3+ + Sm ↔ 3Sm2+ reaction. The results were used to determine the particular mechanism of currentless transfer of samarium in the chloride melt onto a substrate of a more electropositive metal (in particular, onto nickel).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bfd119f9372114d89c232f59a80aead6 https://doi.org/10.1134/s0036024411030204 Zobrazit plný text záznamu Full text from SpringerLink