Green-light photocatalytic reduction using dye-sensitized TiO2and transition metal nanoparticles

Autor:	Ralph Mild, Burkhard König, Heiko Siegmund, Stefan Füldner, Josef Schroeder, Michael Gruber
Rok vydání:	2010
Předmět:	Trace Amounts Nanoparticle chemistry.chemical_element Photochemistry Pollution Catalysis Metal Nitrobenzene chemistry.chemical_compound chemistry Transition metal visual_art Photocatalysis visual_art.visual_art_medium Environmental Chemistry Platinum
Zdroj:	Green Chem.. 12:400-406
ISSN:	1463-9270 1463-9262
DOI:	10.1039/b918140g
Popis:	Nitrobenzenes are cleanly reduced to anilines using Ru-sensitized TiO2 photocatalysts and green light irradiation, if very small amounts of transitions metal salts are added, which form metal nanoparticles of narrow size distribution under the experimental conditions. The catalyst system is prepared by simple mixing of the components and is therefore easy to apply in organic synthesis. As light sources, commercial high power LEDs or sunlight are used. We report the optimization of the reaction conditions, the effect of trace amounts of added metal salts and demonstrate the use of green light photoreduction in the conversion of several nitrobenzene derivatives.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bfc932434e93d26fa1da1119dd111764 https://doi.org/10.1039/b918140g Zobrazit plný text záznamu