Metal-chloroglynate ionic liquids: Catalytic application for friedel-crafts [F–C] reactions
| Autor: | Ramasamy Shanmugapriya, Parasuraman Karthikeyan, Selvarasu Uthayanila, Gopalsamy Selvaraj Ganesh |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
010405 organic chemistry
Organic Chemistry Inorganic chemistry 010402 general chemistry 01 natural sciences Chloride 0104 chemical sciences Catalysis Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Yield (chemistry) Drug Discovery Ionic liquid Electrochemistry visual_art.visual_art_medium medicine Physical and Theoretical Chemistry Benzene Friedel–Crafts reaction medicine.drug Reusability |
| Zdroj: | Journal of the Indian Chemical Society. 98:100081 |
| ISSN: | 0019-4522 |
| DOI: | 10.1016/j.jics.2021.100081 |
| Popis: | Various metal-containing ionic liquids were used as catalysts for Friedel-Crafts reactions. The reaction of R-X with benzene in the presence of M-IL (M = Fe, Zn, Cd, Cu) along with 1-glycyl-3-methylimidazolium chloride ([Gmim] Cl) ionic liquid, leads to the development of several key intermediates. Among them, metal-iron showed higher catalytic activity without organic solvents. This technique features high yield, a simple product isolation, ILs reusability and reduced waste discharge, thus rendering this catalytic system both effective and natural friendly. |
| Databáze: | OpenAIRE |
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