Z-Stereoselective Peterson olefination of ketones

Autor: Alexei V. Buevich, N. Ya. Grigorieva, A. M. Moiseenkov, O. A. Pinsker
Rok vydání: 1995
Předmět:
Zdroj: Russian Chemical Bulletin. 44:492-499
ISSN: 1573-9171
1066-5285
Popis: A highly-stereoselective method (90 % of theZ-isomer) was developed for the Peterson olefination of ketones with nerylacetone (1) as an example. The method is based on the introduction of a PhS group, which is removed after completion of the reaction, at the ketone C(3) atom.
Databáze: OpenAIRE