Z-Stereoselective Peterson olefination of ketones
Autor: | Alexei V. Buevich, N. Ya. Grigorieva, A. M. Moiseenkov, O. A. Pinsker |
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Rok vydání: | 1995 |
Předmět: | |
Zdroj: | Russian Chemical Bulletin. 44:492-499 |
ISSN: | 1573-9171 1066-5285 |
Popis: | A highly-stereoselective method (90 % of theZ-isomer) was developed for the Peterson olefination of ketones with nerylacetone (1) as an example. The method is based on the introduction of a PhS group, which is removed after completion of the reaction, at the ketone C(3) atom. |
Databáze: | OpenAIRE |
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