Activity of Mixed Valence Copper Cyanide Metal–Organic Framework in the Oxidation of 3,5-di-Tert-Butylcatechol with Hydrogen Peroxide

Autor:	Safaa El-din H. Etaiw, M. Hassanein, Mohamed M. El-bendary, Sahar H. El-Khalafy
Rok vydání:	2014
Předmět:	Terephthalic acid Polymers and Plastics Cyanide Inorganic chemistry Redox Catalysis chemistry.chemical_compound chemistry Catalytic oxidation Polymer chemistry Materials Chemistry Metal-organic framework Hydroxyl radical Hydrogen peroxide
Zdroj:	Journal of Inorganic and Organometallic Polymers and Materials. 25:664-670
ISSN:	1574-1451 1574-1443
Popis:	The activity of the metal–organic framework (MOF) {[CuI(CN)(phen)2·CuII(CN)2·(phen)]·5H2O} containing 1,10-phenanthroline ligand (phen) has been investigated for the oxidation of 3,5-di-tert-butylcatechol (3,5-DTBCH2) to 3,5-di-tert-butyl-o-benzoquinone (3,5-DTBQ) with hydrogen peroxide. The effects of pH and concentration of catalyst, hydrogen peroxide and substrate on the oxidation reaction and yield of the reaction product have been studied. Kinetic studies indicate pseudo first-order rate with respect to the 3,5-DTBCH2 concentration (kobs = 0.113 min−1). Disodium salt of terephthalic acid photoluminescence probing technology indicated the formation of the hydroxyl radical as the reactive oxygen species in the MOF/H2O2—system. A mechanism for the oxidation reaction has been discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bf66a7aac75a17834031dba640b2365e https://doi.org/10.1007/s10904-014-0139-4 Zobrazit plný text záznamu Full text from SpringerLink