The photochemistry of proaporphines: a new route to the aporphines

Autor:	S. Fazal Hussain, Maurice Shamma, G. ManiKumar, M. Tariq Siddiqui
Rok vydání:	1980
Předmět:	Chemistry Organic Chemistry Drug Discovery Pakistanamine Organic chemistry Aporphines Biochemistry Pronuciferine Catalysis
Zdroj:	Tetrahedron Letters. 21:723-726
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)71456-0
Popis:	Proaporphines undergo light catalyzed rearrangement. Pakistanamine ( 1 ) is thus converted into lumipakistanine ( 2 ), while pronuciferine ( 7 ) and N-acetylnorpronuciferine ( 8 ) afford the corresponding C-9 hydroxylated aporphines 9 and 10 . Possible biogenetic schemes for the formation of C-8, C-9-, and C-8,9-substituted aporphines are presented.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bf65e07d33dfecf9a7f244fee004185f https://doi.org/10.1016/s0040-4039(00)71456-0 Zobrazit plný text záznamu