Regioselectivity of the allylation of benzothiophene

Autor: Yu. N. Radyukin, A. Karakhanov, Alexander V. Anisimov, Yu. N. Luzikov, V. M. Nikolaeva, E. A. Viktorova
Rok vydání: 1977
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds. 13:1296-1298
ISSN: 1573-8353
0009-3122
Popis: The reaction of benzothiophene with allyl halides in the presence of silver trichloroacetate in chlorine-containing hydrocarbons was investigated. It was established by gas-liquid chromatography and 13C NMR and mass spectrometry that 3-allylbenzothiophene and diallylbenzothiophene are formed in this case. The 13C NMR spectra were interpreted on the basis of an additive scheme with the utilization of benzothiophene, thiophene, and 2- and 3-allylthiophenes as models.
Databáze: OpenAIRE