Regioselectivity of the allylation of benzothiophene
Autor: | Yu. N. Radyukin, A. Karakhanov, Alexander V. Anisimov, Yu. N. Luzikov, V. M. Nikolaeva, E. A. Viktorova |
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Rok vydání: | 1977 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 13:1296-1298 |
ISSN: | 1573-8353 0009-3122 |
Popis: | The reaction of benzothiophene with allyl halides in the presence of silver trichloroacetate in chlorine-containing hydrocarbons was investigated. It was established by gas-liquid chromatography and 13C NMR and mass spectrometry that 3-allylbenzothiophene and diallylbenzothiophene are formed in this case. The 13C NMR spectra were interpreted on the basis of an additive scheme with the utilization of benzothiophene, thiophene, and 2- and 3-allylthiophenes as models. |
Databáze: | OpenAIRE |
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