Kinetics of the liquid-phase oxidation of 1,4-dioxane in the presence of inhibitors

Autor:	G. R. Baimuratova, Rustam L. Safiullin, L. R. Yakupova, V. R. Khairullina, A. Ya. Gerchikov
Rok vydání:	2008
Předmět:	Kinetics Liquid phase General Chemistry 1 4-Dioxane Atmospheric temperature range Chain termination Photochemistry Catalysis Computer Science Applications chemistry.chemical_compound Reaction rate constant chemistry Modeling and Simulation Chain reaction
Zdroj:	Kinetics and Catalysis. 49:366-370
ISSN:	1608-3210 0023-1584
DOI:	10.1134/s0023158408030075
Popis:	The kinetics of 1,4-dioxane oxidation initiated by azodiisobutyronitrile in the temperature range from 323 to 353 K are studied from the rate of oxygen absorption. The oxidation proceeds in the regime of a nonbranched chain reaction with quadratic-law chain termination. The apparent rate constants (fk7) of 1,4-dioxane oxidation inhibition by 2,6-ditert-butyl-4-methylphenol and quercitin are measured. Quercitin is not inferior to ionol in inhibition efficiency.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bf51ceaddc704910e8f25a248e3b08ff https://doi.org/10.1134/s0023158408030075 Zobrazit plný text záznamu Plný text ve formátu PDF