Supramolecular xerogel linked with cobalt(II) ions: A facile method toward O2 storage and catalyzation of cyclohexene oxidation
| Autor: | Jide Wang, Fan Yue, Yi Zhang, Ting He, Xiao-Juan Wang, Rujuan Shen, Peng Xue, Yana Wei, Huiqiong Wu |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Cyclohexene
Supramolecular chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Toluene Redox 0104 chemical sciences Catalysis Solvent chemistry.chemical_compound Colloid and Surface Chemistry chemistry Polymer chemistry 0210 nano-technology Cobalt Oxygen binding |
| Zdroj: | Colloids and Surfaces A: Physicochemical and Engineering Aspects. 506:514-518 |
| ISSN: | 0927-7757 |
| DOI: | 10.1016/j.colsurfa.2016.06.048 |
| Popis: | This paper introduces a tripeptide (β-Asp-Phe-Phe, abbreviation β-AspFF) which can self-assemble into long nanofibrils in toluene solvent and further entangle to organogels. The nanofibrils of β-AspFF can serves as ligands to incorporate with Co(II) in the organogels. After being re-immersed into HFIP-H2O mixed solution (Volume Ratio, 1:1), the β-AspFF-Co(II) xerogel exhibited decent oxygen binding properties. Impressively, in comparing with β-AspFF-Co(II) complex, the β-AspFF-Co(II) xerogel proved to be a higher efficient catalyst for catalyzing cyclohexene oxidation reaction. We therefore suppose that the porous and nanofibrils structure of the xerogel plays a key role to improve the catalytic behavior of β-AspFF-Co(II) complex. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect