Synthesis and characterization of Ge- and Sn-containing ADMET polymers

Autor: Aydogdu Cemil, Karabulut Solmaz, Yavuz İmamoğlu, Düz Bülent
Rok vydání: 2006
Předmět:
Zdroj: Journal of Molecular Catalysis A: Chemical. 254:186-191
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2005.12.046
Popis: A series of dienes containing the germanium and tin moiety were synthesized and their acyclic diene metathesis (ADMET) polymerization was investigated in the presence of electrochemically reduced tungsten-based catalyst system. All monomer and polymer structures were characterized by 1 H and 13 C NMR spectroscopy. Average molecular weights are determined by GPC. Glass transition temperatures of polymers were determined by DSC. The results in this work are comparing with those obtained by the other catalyst systems.
Databáze: OpenAIRE