| Autor: | Marie‐Odile Sepulchre, Nicolas Spassky, Maurice Sepulchre, Jasna Djonlagić, Mihailo S. Jaćović |
|---|---|
| Rok vydání: | 1988 |
| Předmět: |
Fumaric acid
Condensation polymer Maleic acid Potassium Side reaction chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Polyester chemistry.chemical_compound chemistry Polymer chemistry Organic chemistry Solvent effects 0210 nano-technology Glass transition |
| Zdroj: | Die Makromolekulare Chemie. 189:1485-1492 |
| ISSN: | 0025-116X |
| DOI: | 10.1002/macp.1988.021890702 |
| Popis: | A series of aliphatic polymaleates was prepared by polycondensation of potassium maleate with α,ω-dibromoalkanes Br(CH2)n Br (n = 1, 2, 3, 4, 5, 6, 8 and 10) in 1-methyl-2-pyrrolidone. In practically all cases the formation of high-molecular-weight polyesters is accompanied by the production of substantial amounts of cyclic oligomers. This polycondensation reaction, carried out at moderate temperature, allows to obtain configurationally pure polymaleates. The resulting unsaturated polyesters are highly viscous liquids with glass transition temperatures below room temperature. |
| Databáze: | OpenAIRE |
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