Addition Radicalaire du Propanal à Divers Alcènes et Cyclènes: Aspects Stériques et Polaires

Autor:	M. Cazaux, Robert Lalande, I. Tabbaa
Rok vydání:	2010
Předmět:	Steric effects chemistry.chemical_classification Ketone Double bond General Chemistry Benzoyl peroxide Photochemistry Aldehyde Medicinal chemistry Adduct chemistry.chemical_compound chemistry medicine Methylene Free-radical addition medicine.drug
Zdroj:	Bulletin des Sociétés Chimiques Belges. 92:1011-1018
ISSN:	0037-9646
DOI:	10.1002/bscb.19830921110
Popis:	Free radical addition of propanal to double bonds, initiated by benzoyl peroxide, mainly leads to two adducts, an aldehyde and a ketone, when the double bond has a methylene group; these results are explained in terms of polar effects in the free radical transfert reactions. When the double bond has no methylene group, only the ketonic adduct is obtained; the steric effects in the free radical addition step explain these results.
Databáze:	OpenAIRE
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