Magnetic rotation spectroscopy of tetraphenyl tin

Autor:	Bryan E. Kohler, Peter Esherick
Rok vydání:	1974
Předmět:	Chemistry Magnetic circular dichroism Magnetic rotation Analytical chemistry Physics::Optics General Physics and Astronomy Tetraphenyl tin Molecular physics Symmetry (physics) Singlet state Physical and Theoretical Chemistry Spectroscopy Dispersion (chemistry) Single crystal
Zdroj:	The Journal of Chemical Physics. 61:4490-4499
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.1681766
Popis:	Magneto‐optical rotary dispersion and magnetic circular dichroism studies of the lowest energy singlet to triplet transition of single crystal tetraphenyl tin which clearly demonstrate the feasibility of magnetic rotation spectroscopy on uniaxial organic molecular crystals are reported. Special considerations for these types of experiments are discussed. A simple model where only the field‐induced mixing of the triplet sublevels is considered completely accounts for the observed magneto‐optical activity. Symmetry assignments derived from these studies agree with those reported earlier.
Databáze:	OpenAIRE
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