Temperature and concentration dependences of the activity coefficients of electrolytes
Autor: | G. B. Sidel’nikov, N. A. Tikhonov |
---|---|
Rok vydání: | 2017 |
Předmět: |
Activity coefficient
Materials science 010304 chemical physics Zero (complex analysis) Thermodynamics Electrolyte 010402 general chemistry 01 natural sciences 0104 chemical sciences Ion Strong electrolyte Character (mathematics) 0103 physical sciences Physics::Chemical Physics Physical and Theoretical Chemistry |
Zdroj: | Russian Journal of Physical Chemistry A. 91:1890-1895 |
ISSN: | 1531-863X 0036-0244 |
DOI: | 10.1134/s0036024417100387 |
Popis: | A model has been suggested that describes the interaction of hydrated ions in electrolytes and allows the calculation of the main physical effects. The model explains the character of the curves of the activity coefficients. Binary solutions of uni-univalent electrolytes at concentrations from zero to several moles per liter and at temperatures from zero to a few dozens of degrees were studied. The results of simulation were verified by comparing them with many literature data. |
Databáze: | OpenAIRE |
Externí odkaz: |