Liquidus temperature measurements for modeling oxide glass systems relevant to nuclear waste vitrification

Autor:	Jonathan Hanni, John D. Vienna, Kevin Bc Minister, Diana N. Tran, Pavel R. Hrma, Jarrod V. Crum, Eric D. Pressly
Rok vydání:	2005
Předmět:	Materials science Mechanical Engineering Oxide Radioactive waste Thermodynamics Liquidus Condensed Matter Physics Temperature measurement Silicate chemistry.chemical_compound chemistry Mechanics of Materials Phase (matter) General Materials Science Vitrification Ternary operation Nuclear chemistry
Zdroj:	Journal of Materials Research. 20:3346-3357
ISSN:	2044-5326 0884-2914
DOI:	10.1557/jmr.2005.0424
Popis:	Liquidus temperatures (TL) were measured, and primary phases were determined for 50 (from an initial test matrix of 76) compositions within the Al2O3–B2O3–CaO–Na2O–SiO2 glass-forming system and its constituent ternary subsystems. Strong linear correlations have been found between composition and TL for melts within the same primary phase fields. The TL and primary phase data are being used to develop and refine a modified associate species model (ASM). The impacts of Fe2O3, Li2O, NiO, ZrO2, Cr2O3, ZnO, and MnO additions on the TL of two baseline glass compositions are reported. These data are intended as benchmarks for further expansion of the ASM or other silicate melt solution models of nuclear waste glasses.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bf1314ba1b87d66184abc6086844e7d2 https://doi.org/10.1557/jmr.2005.0424 Zobrazit plný text záznamu Full text from SpringerLink