DABCO/AgOAc cooperatively catalyzed α-sulfenylation of isocyanoacetates with N-(sulfanyl)succinimides

Autor:	Qiang Liu, Mei-Xin Zhao, Min Shi, Rong-Hui Jiang
Rok vydání:	2019
Předmět:	010405 organic chemistry Organic Chemistry DABCO 010402 general chemistry 01 natural sciences Biochemistry Combinatorial chemistry 0104 chemical sciences Catalysis Succinimides Metal chemistry.chemical_compound chemistry Sulfanyl visual_art Organocatalysis Drug Discovery visual_art.visual_art_medium
Zdroj:	Tetrahedron Letters. 60:668-671
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2019.01.050
Popis:	The first organo/metal cooperatively catalyzed α-sulfenylation of isocyanoacetates with N-(sulfanyl)succinimides has been developed. The reaction condition was suitable to α-aryl and alkyl-substituted isocyanoactates as well as N-(arylthio)succinimides, affording the corresponding products with high yields (90–96%). Preliminary asymmetric organocatalysis has also been evaluated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bf100be32c85b6b4924bed9c5208f5f7 https://doi.org/10.1016/j.tetlet.2019.01.050 Zobrazit plný text záznamu Full Text from ScienceDirect