Synthesis of poly(ester carbonate) copolymers

Autor:	Y. Kesten, B. T. Debona, D. C. Prevorsek
Rok vydání:	1980
Předmět:	chemistry.chemical_classification Terephthalic acid Carbonic acid chemistry.chemical_compound Dicarboxylic acid chemistry Polymer chemistry Copolymer Molar mass distribution Organic chemistry Polymer Phosgene Chain termination
Zdroj:	Journal of Polymer Science: Polymer Chemistry Edition. 18:75-90
ISSN:	1542-9369 0360-6376
DOI:	10.1002/pol.1980.170180109
Popis:	The synthesis of poly(ester carbonate) copolymers based on bisphenol A, terephthalic acid, and phosgene is reviewed, and a new synthetic route is described leading to polymers which are different from those obtained by methods described in the literature. The most important features of the new method are quantitative incorporation of the dicarboxylic acid into the polymer and absence of undersirable side reactions. Synthesis of the random copolymer in which the dicarboxylic acid and carbonic acid groups are present in about equal molar amounts is discussed. Solution properties, effects of Mn and copolymer composition on Tg, sequence length distribution, the effect of ester interchange reactions on molecular weight distribution, and effects of monofunctional chain termination on molecular weight of the final product are also discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bee9b0a53eb065ab61e1b1d20d5ad468 https://doi.org/10.1002/pol.1980.170180109 Zobrazit plný text záznamu Plný text