Synthesis of aromatic polybenzoxazoles by reducing polyheterocyclization of poly-[(o-nitro)esters]

Autor: Z. Sh. Dzhaparidze, Alexander L. Rusanov, I. M. Gverdtsiteli, G.M. Tseitlin, V.V. Korshak, A.Ya. Chernikhov, D. S. Tugushi
Rok vydání: 1979
Předmět:
Zdroj: Polymer Science U.S.S.R.. 21:2051-2056
ISSN: 0032-3950
DOI: 10.1016/0032-3950(79)90116-3
Popis: A new method was developed for the synthesis of polybenzoxazoles, which is based on the interaction of dicarboxylic acid dichlorides with bis-[(o-nitro)phenols], the reduction of o-nitrosubstituents of poly[(o-nitro)esters] obtained and the simultaneous ring formation of poly-[(o-amino)esters] to form polybenzoxazoles. The method developed enables high molecular weight film forming polymers to be obtained under homogeneous conditions.
Databáze: OpenAIRE