Kinetics of oxidative polymerization inhibited by antioxidants. Limiting concentrations of antioxidants, critical rate of initiation and critical concentration of monomer
Autor: | N.N. Tvorogov |
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Rok vydání: | 1983 |
Předmět: | |
Zdroj: | Polymer Science U.S.S.R.. 25:282-294 |
ISSN: | 0032-3950 |
DOI: | 10.1016/0032-3950(83)90203-4 |
Popis: | Equations have been obtained for the rate of oxidation and polymerization of a monomer, the induction period and other parameters of the reaction of polymerization occurring at any concentration of the antioxidant. The conditions in which the antioxidant acts as an oxygen co-inhibitor are defined. The values of the lower and upper limits of the concentration of antioxidant, the critical rate of initiation and the critical concentration of the monomer are established. |
Databáze: | OpenAIRE |
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