Kinetics of oxidative polymerization inhibited by antioxidants. Limiting concentrations of antioxidants, critical rate of initiation and critical concentration of monomer

Autor: N.N. Tvorogov
Rok vydání: 1983
Předmět:
Zdroj: Polymer Science U.S.S.R.. 25:282-294
ISSN: 0032-3950
DOI: 10.1016/0032-3950(83)90203-4
Popis: Equations have been obtained for the rate of oxidation and polymerization of a monomer, the induction period and other parameters of the reaction of polymerization occurring at any concentration of the antioxidant. The conditions in which the antioxidant acts as an oxygen co-inhibitor are defined. The values of the lower and upper limits of the concentration of antioxidant, the critical rate of initiation and the critical concentration of the monomer are established.
Databáze: OpenAIRE