Mechanism of Synthesis and Structure Formation of Hybrid Oligomers Based on Complex Oligophenylene Compounds with Metals
| Autor: | O. V. Buriachek, Svitlana Kukharenko, Y. M. Romanenko, O. M. Kaidash, Eugen Pashchenko, S. V. Skorokhod, Yu. Yu. Rumiantseva, Denys Savchenko |
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| Rok vydání: | 2020 |
| Předmět: |
010302 applied physics
Reaction mechanism Materials science Structure formation Dimethyl sulfoxide 02 engineering and technology 01 natural sciences Combinatorial chemistry Reaction product Inorganic Chemistry Metal chemistry.chemical_compound 020303 mechanical engineering & transports 0203 mechanical engineering chemistry visual_art Yield (chemistry) 0103 physical sciences visual_art.visual_art_medium General Materials Science |
| Zdroj: | Journal of Superhard Materials. 42:443-445 |
| ISSN: | 1934-9408 1063-4576 |
| DOI: | 10.3103/s106345762006009x |
| Popis: | The reaction mechanism of the formation of hybrid oligomers based on complexes compounds of metal and oligophenylene is considered. The structure of compounds formed in such a reaction is determined. The effect of the addition of dimethyl sulfoxide on the increase in the yield of the main reaction product was found, and a mechanism of this effect was proposed, based on the change in the conformational features of oligophenylene in the synthesis process. The produced oligomers are promising as binders for composites of superhard materials. |
| Databáze: | OpenAIRE |
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