Stereospecific Oxidation of Alkanes Catalyzed by Fe2( -Carboxylato) Complexes, which Model Some of the Structural Features of the Active Center of Methane Monooxygenase

Autor:	V. M. Trukhan, Albert A. Shteinman, E. A. Gutkina
Rok vydání:	2003
Předmět:	Alkane chemistry.chemical_classification biology Ligand Methane monooxygenase Stereochemistry Active site General Chemistry Catalysis Computer Science Applications Active center Stereospecificity Hydrocarbon chemistry Modeling and Simulation biology.protein
Zdroj:	Kinetics and Catalysis. 44:751-752
ISSN:	0023-1584
DOI:	10.1023/b:kica.0000009049.29195.07
Popis:	Binuclear μ-oxalate iron complexes (1 and 2) that model the Fe2(μ-COO) nucleus of the methane monooxygenase active center catalyze the stereospecific transfer of an oxygen atom from H2O2 to C–H bonds in alkanes. Due to the framework nature of the ligand, the binuclear structure of the iron complex is retained in the solution. These data reliably confirm the fact that the catalytic reaction occurs at a binuclear center via a mechanism with the participation of both iron atoms.
Databáze:	OpenAIRE
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