Chemiluminescent reactions of Ca with hydrogen peroxide

Autor:	R.P. Kampf, M.D. Oberlander, J. M. Parson
Rok vydání:	1991
Předmět:	chemistry.chemical_classification General Physics and Astronomy Photochemistry law.invention chemistry.chemical_compound chemistry law Metastability Excited state Physical and Theoretical Chemistry Ground state Hydrogen peroxide Molecular beam Inorganic compound Chemiluminescence
Zdroj:	Chemical Physics Letters. 176:385-389
ISSN:	0009-2614
DOI:	10.1016/0009-2614(91)90048-e
Popis:	Electronic chemiluminescence has been observed in reactions of Ca in ground and metastable ( 3 P o ) states with H 2 O 2 in beam-gas experiments. Ground state Ca yields predominantly CaO emission, while excited state Ca gives CaOH. The ground state chemiluminescent cross section falls more steeply with increasing collisional energy. It is suggested that the different behavior of the atomic states can be attributed to a varying amount of time available during collisions for the H atom to migrate to form H 2 O.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::beb67a85af8c48c4ad67b9dfa6ecdf3c https://doi.org/10.1016/0009-2614(91)90048-e Zobrazit plný text záznamu