Molecular structure of perfluoroadamantane from gas-phase electron diffraction

Autor:	Hajime Baba, J. Brunvoll, Takaaki Sonoda, István Hargittai, Takashi Abe
Rok vydání:	1998
Předmět:	Chemistry Adamantane Organic Chemistry Analytical Chemistry Gas phase Inorganic Chemistry Perfluoroadamantane Bond length Crystallography chemistry.chemical_compound Molecular geometry Electron diffraction Molecule Spectroscopy
Zdroj:	Journal of Molecular Structure. 445:55-58
ISSN:	0022-2860
Popis:	The following bond lengths ( r g ) and bond angles have been determined for perfluoroadamantane from gas-phase electron diffraction: CC 1.560 ± 0.003, C(F 2 )F 1.340 ± 0.005, C(F)F 1.363 ± 0.010 A , CC(F 2 )C 107.7 ± 0.9, CC(F)C 110.3 ± 0.4, FC(F 2 )F 106.9 ± 0.4, C(F 2 )CF 108.6 ± 0.4 and C(F)CF 110.5 ± 0.2°. Perfluorination is found to expand the adamantane cage, characterized by a 0.02 A lengthening of the CC bonds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::beb0929c9e3842fb5d1e6ee35df6a7b0 https://doi.org/10.1016/s0022-2860(97)00412-2 Zobrazit plný text záznamu Full Text from ScienceDirect