Aminimides. V. Preparation and polymerization studies of trimethylamine-4-vinylbenzimide

Autor:	B. M. Culbertson, R. E. Freis, E. A. Sedor, S. Dietz
Rok vydání:	1968
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Polymerization Polymer chemistry General Engineering Copolymer Trimethylamine Molecule Reactivity (chemistry) Polymer Methyl methacrylate Styrene
Zdroj:	Journal of Polymer Science Part A-1: Polymer Chemistry. 6:2197-2207
ISSN:	1542-9350 0449-296X
DOI:	10.1002/pol.1968.150060816
Popis:	Trimethylamine-4-vinylbenzimide (TAVBI) has been homo- and copolymerized with styrene, methyl methacrylate, and hydroxypropyl methacrylate by free-radical initiators to soluble, low molecular weight polymers containing pendant aminimide groups along the backbone of the polymer molecules. The reactivity ratios in the copolymerization of TAVBI (M1) with styrene (M2) were determined: r1 = 0.63 ± 0.07, r2 = 0.47 ± 0.05. The Alfrey-Price Q and e values for TAVBI were also calculated: Q = 0.88, e = 0.31. This introductory work indicates that TAVBI has potential for the preparation of a wide variety of reactive polymers.
Databáze:	OpenAIRE
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