Preparation and characterization of H1–e rhodium films

Autor:	Philip N. Bartlett, Jan Marwan
Rok vydání:	2003
Předmět:	Chemistry chemistry.chemical_element General Chemistry Condensed Matter Physics Rhodium Chemical engineering Mechanics of Materials Liquid crystal Lyotropic liquid crystal Phase (matter) Basic solution Lyotropic Organic chemistry General Materials Science Cyclic voltammetry Mesoporous material
Zdroj:	Microporous and Mesoporous Materials. 62:73-79
ISSN:	1387-1811
DOI:	10.1016/s1387-1811(03)00394-9
Popis:	Mesoposous films of rhodium were prepared by electrochemical deposition from rhodium (III) chloride dissolved in the H1 lyotropic liquid crystalline phase of octaethyleneglycol monohexadecyl ether (C16EO8) or Brij � 56. Characterization of the electrochemically deposited films using SEM, TEM, small angle X-ray diffraction and cyclic voltammetry show that they are smooth, strongly adherent, with a high surface area (32 m 2 g 1 ) and containing a regular hexagonal array of cylindrical pores with a pore centre to pore centre separation of around 6 nm. Preliminary studies show that the films can be used to carry out the electrochemical reduction of nitrate in basic solution. � 2003 Elsevier Inc. All rights reserved.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bea64c5d80b57ca9658c50a5c031c5df https://doi.org/10.1016/s1387-1811(03)00394-9 Zobrazit plný text záznamu Full Text from ScienceDirect