Reaction of N,N′-bis(trimethylsilyl)dicyandiamide with bis(η5-cyclopentadienylvanadium) dichloride

Autor: S. V. Zimina, V. F. Ur’yash, Alexandr V. Piskunov, S. V. Saprykina, E. M. Moseeva, L. B. Loginova, A. S. Gordetsov
Rok vydání: 2011
Předmět:
Zdroj: Russian Journal of General Chemistry. 81:658-662
ISSN: 1608-3350
1070-3632
Popis: 1,3,5-Tris[bis(η5-cyclopentadienyl)chlorovanadium]melamin is prepared in high yield by the reaction of N,N′-bis(trimethylsilyl)dicyandiamide with bis(η5-cyclopentadienylvanadium) dichloride in tetrahydrofuran. As side products, trimethylchlorosilane and cyclopentadiene formed. Reaction of N,N′-bis(trimethylsilyl) dicyandiamide with benzoyl chloride results in the formation of tris(benzoyl)melamin.
Databáze: OpenAIRE