Chlorine-Influenced Changes in the Molecular Inclusion and Packing Properties of a Diquinoline Host

Autor:	Donald C. Craig, Jason Ashmore, Roger Bishop, Marcia L. Scudder
Rok vydání:	2006
Předmět:	Chloroform Dimer General Chemistry Crystal structure Condensed Matter Physics Crystal engineering Toluene Inclusion compound chemistry.chemical_compound Crystallography chemistry Molecule Organic chemistry General Materials Science Acetophenone
Zdroj:	Crystal Growth & Design. 7:47-55
ISSN:	1528-7505 1528-7483
DOI:	10.1021/cg060338q
Popis:	Chloro-substituted diquinoline dibromide 6 is a versatile host molecule that includes guest molecules of different functionality in several different ways. The crystal structures of 6 and its lattice inclusion compounds with carbon disulfide, dichloromethane, acetone, chloroform, benzene, and toluene are reported and analyzed in crystal engineering terms. Also described is the quinolinium inclusion compound (11)·(acetophenone). The inclusion properties of 6, and the ways that it achieves these, are very different from those of its non-chlorinated parent, 4. Different types of aromatic interfacial packing are discussed. There is far greater dependence on these types of interactions and a complete absence of the aromatic edge−edge C−H···N dimer motif in the crystal structures of 6.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::be68232859e1360f9003d04aa74c42ec https://doi.org/10.1021/cg060338q Zobrazit plný text záznamu