CRYSTAL AND MOLECULAR STRUCTURE AND SOLID STATE NMR STUDIES OF BIS(5,5-DIMETHYL-2-OXO-1,3,2-DIOXAPHOSPHORINAN-2-YL) SELENIDE

Autor:	Roman Dembinski, Aleksandra Skowrońska, Michał W. Wieczorek, Marek J. Potrzebowski, JarosŁAw Błaszczyk
Rok vydání:	1995
Předmět:	Organic Chemistry Cyclohexane conformation chemistry.chemical_element Triclinic crystal system Biochemistry Inorganic Chemistry Crystal chemistry.chemical_compound Crystallography chemistry Solid-state nuclear magnetic resonance Selenide X-ray crystallography Molecule Selenium
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 102:15-24
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426509508042537
Popis:	The structural investigation of the phosphoroorganic selenium-containing title compound C10H20O6P2Se (1) was carried out. The structure of 1 has been determined by X-ray analysis and correlated with the solid state NMR studies, its purity and identity was confirmed by elemental analysis. The following crystal data were found: triclinic, P1, a = 5.6557(6) A, b = 10.2717(8) A, c = 13.761(1) A, α = 105.580(7)β, p = 90.992(7)°, γ = 101.745(8)°, and Z = 2. Two six-membered rings in the molecule of 1 are in the chair conformation. The selenium atom which bridges the rings is situated axially with respect to both rings. The exocyclic oxygens are, consequently, in equatorial positions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::be5e5a7cd77b0afd82104c5dce17d561 https://doi.org/10.1080/10426509508042537 Zobrazit plný text záznamu