Cycloadditionen von Benzothiet und aromatischen Nitroso‐Verbindungen

Autor:	Herbert Meier, H.‐L. Eckes, Klaus Saul, Dominic E. Jacob
Rok vydání:	1993
Předmět:	Inorganic Chemistry chemistry.chemical_compound Primary (chemistry) Nitroso Compounds Sulfinamide Bicyclic molecule Chemistry Stereochemistry Regioselectivity Ring (chemistry) Medicinal chemistry Cycloaddition
Zdroj:	Chemische Berichte. 126:775-778
ISSN:	0009-2940
DOI:	10.1002/cber.19931260331
Popis:	Cycloaddition Reactions of Benzothiete and Aromatic Nitroso Compounds The new heterocyclic ring systems 4H-3,1,2-benzoxathiazines 4 and 2,3-dihydro-1,2-benzothiazol 1-oxides 6 can be synthesized by cycloaddition of benzothiete (1) and aromatic nitroso compounds 3. The regioselectivity of the primary step and the secondary thermal or acid-catalyzed rearrangements are discussed.
Databáze:	OpenAIRE
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