Synthesis of medium-sized carbocyclic ketones via the intramolecular B-alkyl Liebeskind–Srogl coupling reaction

Autor: Kazuhiro Tsuna, Masahisa Nakada, Naoyoshi Noguchi
Rok vydání: 2011
Předmět:
Zdroj: Tetrahedron Letters. 52:7202-7205
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2011.10.148
Popis: Synthesis of medium-sized carbocyclic ketones via the intramolecular B-alkyl Liebeskind–Srogl coupling reaction is described. The sequence of hydroboration of ω-alkenyl thiol ester with 9-BBN and the Liebeskind–Srogl reaction results in the formation of medium-sized carbocyclic ketones with good yield.
Databáze: OpenAIRE