Poly(vinylidene fluoride) Nanocomposites with Simultaneous Organic Nanodomains and Inorganic Nanoparticles
| Autor: | Chenyang Xing, Jingye Li, Yongjin Li, Xingyi Huang, Yanyuan Wang |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Tetrafluoroborate
Nanocomposite Materials science Polymers and Plastics Organic Chemistry Nanoparticle 02 engineering and technology Carbon black Dielectric 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences law.invention Inorganic Chemistry chemistry.chemical_compound chemistry Chemical engineering law Ionic liquid Polymer chemistry Materials Chemistry Crystallization 0210 nano-technology Fluoride |
| Zdroj: | Macromolecules. 49:1026-1035 |
| ISSN: | 1520-5835 0024-9297 |
| DOI: | 10.1021/acs.macromol.5b02429 |
| Popis: | Nanostructured polymeric dielectric composites, based on poly(vinylidene fluoride) (PVDF), conductive carbon black (CB), and an unsaturated ionic liquid (IL), 1-vinyl-3-ethylimidazolium tetrafluoroborate ([VEIM][BF4]), were fabricated by melt blending and electron beam irradiation (EBI) methods. Our strategy forms simultaneous double nanophases in the PVDF matrix, that is, homogeneously dispersed CB nanoparticles and organic PVDF-g-IL nanodomains. The organic nanodomains were produced by microphase separation of the PVDF-g-IL chains from the PVDF matrix at melt state in the electron beam (EB) irradiated PVDF/IL-CB nanocomposites. Furthermore, the CB nanoparticles were fully adhered with these nanodomains, and novel structures with nanodomains@CB nanoparticle were achieved. Such nanodomains@CB nanoparticle structures showed a synergetic nucleating effect on the PVDF crystallization and led to the formation of dominant nonpolar α phases in the nano-PVDF/IL-CB composites. Because of the nanodomains adhesion ... |
| Databáze: | OpenAIRE |
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