| Popis: |
The distribution of units and composition heterogeneity of copolymers were accurately calculated for the first time using the kinetic system of complex-radical copolymerization, when, in parallel with a single introduction of monomers in the chain, it is also possible to add them in pairs as a complex to the end of the chain. It was shown that although microstructure is not described by Markov statistics, there is a simple algorithm available for calculating probabilities of arbitrary sequences of units. A normal composition distribution function was shown and its parameters were indicated. |
