Water structure in concentrated lithium chloride solutions
| Autor: | G. W. Neilson, Alan K. Soper, R. H. Tromp |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Hydrogen bond Stereochemistry Intermolecular force Neutron diffraction Analytical chemistry General Physics and Astronomy Radial distribution function chemistry.chemical_compound chemistry Intramolecular force Lithium chloride Physical and Theoretical Chemistry Inorganic compound |
| Zdroj: | The Journal of Chemical Physics. 96:8460-8469 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.462298 |
| Popis: | The radial pair distribution functions gHH(r) and gOH(r) (to a good approximation) of 1 and 10 m solutions of lithium chloride in water have been obtained from neutron diffraction. It turns out that the intermolecular water structure in a solution of 10 m is affected considerably by the presence of ions—the number of hydrogen bonds is about 70% lower than in pure water. The intermolecular water structure in 1 m lithium chloride as well as the intramolecular water structure in both 1 and 10 m lithium chloride is not distinguishable from that of pure water in any measurable extent. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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