A degraded glycol-substitutediso-closoten-vertex ruthenaborane: [(PPh3)HClRuB9H5(OCH2CH2OH)2(PPh3)2].1.2CHCl3

Autor:	Z.-E. Huang, Jie Sun, J.-D. Wei, R.-S. Jin, P.-J. Zheng, J.-M. Dou, C.-H. Hu, H.-J. Yao
Rok vydání:	1999
Předmět:	Chloroform Chemistry Stereochemistry General Medicine Crystal structure Medicinal chemistry General Biochemistry Genetics and Molecular Biology Vertex (geometry) Metal chemistry.chemical_compound visual_art visual_art.visual_art_medium Molecule Triphenylphosphine
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 55:337-339
ISSN:	0108-2701
Popis:	1-Chloro-1-hydrido-2,6-bis(2-hydroxyethoxy)-1,3,5-tris-(triphenylphosphine)- iso - closo - 1- ruthenadecaborane -chloroform (1/1.2), [RuHCl(C 40 H 45 B 9 O 4 P 2 )(C 18 H 15 P)]-1.2CHCl 3 , is a ruthenaborane based on an iso-closo C 3v stack, with the nine-coordinate metal occupying the six-connected apical position. The {RuB 9 } cage has two B-terminal -OCH2CH20H groups and two PPh3 substituents.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bdff2d9d9172842e89a984c9a085f983 https://doi.org/10.1107/s0108270198013237 Zobrazit plný text záznamu Plný text