A degraded glycol-substitutediso-closoten-vertex ruthenaborane: [(PPh3)HClRuB9H5(OCH2CH2OH)2(PPh3)2].1.2CHCl3
Autor: | Z.-E. Huang, Jie Sun, J.-D. Wei, R.-S. Jin, P.-J. Zheng, J.-M. Dou, C.-H. Hu, H.-J. Yao |
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Rok vydání: | 1999 |
Předmět: | |
Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 55:337-339 |
ISSN: | 0108-2701 |
Popis: | 1-Chloro-1-hydrido-2,6-bis(2-hydroxyethoxy)-1,3,5-tris-(triphenylphosphine)- iso - closo - 1- ruthenadecaborane -chloroform (1/1.2), [RuHCl(C 40 H 45 B 9 O 4 P 2 )(C 18 H 15 P)]-1.2CHCl 3 , is a ruthenaborane based on an iso-closo C 3v stack, with the nine-coordinate metal occupying the six-connected apical position. The {RuB 9 } cage has two B-terminal -OCH2CH20H groups and two PPh3 substituents. |
Databáze: | OpenAIRE |
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