Hydrogen embrittlement in a Mg-Al alloy

Autor: D. G. Chakrapani, E. N. Pugh
Rok vydání: 1976
Předmět:
Zdroj: Metallurgical Transactions A. 7:173-178
ISSN: 2379-0180
0360-2133
DOI: 10.1007/bf02644454
Popis: Experiments are described which demonstrate that a Mg-7.5 wt pct Al alloy is embrittled by both cathodically-generated and gaseous hydrogen. Immersion of unstressed specimens in an aqueous NaCl-K2CrO4 solution is shown to lead to absorption of hydrogen and to a form of internal hydrogen embrittlement similar to that observed in BCC metals. Thus embrittlement was manifested by loss of ductility in tensile tests and by cleavage-like fracture surfaces; vacuum annealing after immersion led to a reduction in hydrogen concentration and to a partial recovery of ductility; and embrittlement was not observed at high strain rates. Embrittled specimens also exhibited delayed failure in both constant-load tensile tests and constant-deflection bend tests. In a second series of experiments, slow crack growth was observed when edge-notched tensile specimens were stressed in ~ lpsig (~ 6.9 × 103 N/m2) dry hydrogen; the fracture surfaces were again cleavage-like in appearance. The significance of these observations is discussed in relation to the stress-corrosion failure of this alloy.
Databáze: OpenAIRE