Synthesis and structural studies of arene ruthenium and Cp*Rh/Cp*Ir complexes containing pyridylpyrazole- and pyridylthiazole-based ligands
| Autor: | S. Sangilipandi, R. Nagarajaprakash, Mahesh Kalidasan, K. Mohan Rao |
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| Rok vydání: | 2016 |
| Předmět: |
Pyrimidine
010405 organic chemistry Metals and Alloys chemistry.chemical_element 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Catalysis Ruthenium Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Pyridine Materials Chemistry visual_art.visual_art_medium Organic chemistry Thiazole Benzene Organometallic chemistry |
| Zdroj: | Transition Metal Chemistry. 41:261-270 |
| ISSN: | 1572-901X 0340-4285 |
| DOI: | 10.1007/s11243-015-0017-0 |
| Popis: | The reactions of [(arene)RuCl2]2 (arene = p-cymene or benzene) and [Cp*MCl2]2 (M = Rh or Ir) with N,N′-bidentate chelating ligands 2-[3-(2-pyridyl)pyrazolyl]pyrimidine (L1) and 4-phenyl-(2-pyridyl)thiazole (L2) leads to the formation of mononuclear complexes of general formula [(arene)/Cp*M(L)Cl]PF6. Eight such complexes have been prepared and characterized by spectroscopic techniques. In addition, five of the complexes were also characterized by single-crystal X-ray diffraction. These complexes have typical piano-stool geometries around the metal center, with five-membered metellacycles in which L1 and L2 both act as N,N′-chelating ligands. Moreover, L1 prefers to coordinate through its pyrimidine and pyrazolyl nitrogen atoms, rather than the pyridine nitrogen. |
| Databáze: | OpenAIRE |
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