Studies on Unsaturated Organosilicon Compounds. I. Syntheses of Organovinylsilanes by Wurtz- Fittig Reaction

Autor:	Motonori Kanazashi
Rok vydání:	1953
Předmět:	Diacetyl peroxide Wurtz–Fittig reaction Infrared spectroscopy Ether General Chemistry Vinyl chloride Metal chemistry.chemical_compound chemistry Trichlorosilane visual_art Polymer chemistry visual_art.visual_art_medium Organic chemistry Organosilicon
Zdroj:	Bulletin of the Chemical Society of Japan. 26:493-496
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.26.493
Popis:	(1) Vinyl chloride and organohalosilanes were shown to react with finely divided metallic sodium in ethyl ether, and trimethyl-, dimethyldi-, triethyl- and dimethylphenyl- vinylsilanes were prepared. Of these, dimethyldi- and dimethylphenyl-vinylsilane are new compounds and their physical constants were given. (2) Infrared spectra of these four organovinylsilanes were obtained and certain characteristic absorption bands were discussed. (3) Trichlorosilane was found to add to these vinylsilanes at the presence of diacetyl peroxide and four new β-trichlorosilylethyl-silanes were prepared and characterized.
Databáze:	OpenAIRE
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